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Hydrofluoric acid

CAS 7664-39-3 · 100/100 · High conf.

Also registered as 4 other CAS numbers

12381-92-9 · 37249-79-9 · 32057-09-3 · 326604-75-5

Hydrofluoric acid chemical structure

Concern score

100/100Critical concern based on regulatory listings.
High confidence

Hydrofluoric acid in plain language

What it is

On cosmetic ingredient lists it appears as “Ammonium hexafluorophosphate”.

Also known as Ammonium hexafluorophosphate · Palmityl trihydroxyethyl propylenediamine dihydrofluoride · Saccharomyces/fluoride ferment · Hydrogen fluoride · fluorane · Fluohydric Acid

Show all 28 names

Fluorhydric Acid · Acide fluorhydrique · Acido fluoridrico · Anhydrous hydrofluoric acid · Antisal 2B · Fluoric acid · Fluorine hydride (FH) · Fluorowodor · Fluorwasserstoff · Fluorwaterstof · Hydrofluoride · Hydrogen fluoride (HF) · Porcelain Conditioner · RCRA waste number U134 · Rubigine · Ultradent Porcelain Etch · fluoridohydrogen · hydrofluoric acid (sara 302/313) (cercla) · hydrofluoric acid (sara iii) · hydrogen fluoride (sara iii) · hydrogen fluoride (sara 302/313) (cercla) · Hydrofluoricum acidum

What it does

Used in consumer products as a pH adjuster.

  • pH adjuster
Is it a concern?
Critical concern: no hazard classifications on record. It is banned in EU cosmetics.

Why it's flagged

Hydrofluoric acid, its normal salts, its complexes and hydrofluorides with exception of those given in Annex III is prohibited in cosmetic products under Annex II of the EU Cosmetics Regulation (EC) 1223/2009.

RestrictedEU EC — banned

The score describes this ingredient's chemical identity — its hazard profile from published classifications and regulatory status — not the safety of any product it appears in.

Regulation

Restrictions first, then routine listings from published regulatory sources.

  • In marketed US drugs
  • EU Annex II — prohibited
  • EU prohibited in cosmetics

Recorded in these product areas

  • Found in consumer products
  • Beauty
  • Cleaning
  • Pharma
  • Industrial
  • EUEC

    Annex II of EU Cosmetics Regulation (EC) 1223/2009: substances prohibited in cosmetic products.

    banned
    View source →
  • EUCosIngActiveCosmetics Regulation annex II / ref 191.
    • Cosmetics Regulation annex II / ref 191.Source →
  • USEPAcommercial use observedEPA CPDat observed this chemical in 450 composition records across product categories including Cleaning and safety, Personal care, Specialty occupational products. EPA CPDat classifies this chemical for functional uses including pH regulating agent.
    • EPA CPDat observed this chemical in 450 composition records across product categories including Cleaning and safety, Personal care, Specialty occupational products. EPA CPDat classifies this chemical for functional uses including pH regulating agent.Source →
  • USFDAmarketed drug occurrenceFDA NDC lists this ingredient in 53 active drug products and 59 total products.
    • FDA NDC lists this ingredient in 53 active drug products and 59 total products.Source →
  • USFDAlisted in openFDA substanceopenFDA substance registry classifies this ingredient as chemical.
    • openFDA substance registry classifies this ingredient as chemical.Source →

Expert safety opinions

No expert opinion on file for Hydrofluoric acid. These are the independent scientific bodies that assess ingredients like this one; we show an opinion only when a record we hold cites it.

  • SCCS

    EU Scientific Committee on Consumer Safety

    No SCCS opinion on file.

  • CIR

    Cosmetic Ingredient Review (US expert panel)

    No CIR safety assessment on file.

Evidence & sources

No graded research studies for Hydrofluoric acid yet. This record is compiled from the published data sources below — registries and regulatory listings, not study findings.

8 data sources

Where this comes from

  • CosIng

    regulatory · updated 2026-09-23

    Open →
  • EU CosIng Cosmetics Regulation Annexes

    regulatory · updated 2010-10-15

    Open →
  • EPA Chemical and Products Database

    exposure · updated jan 24 1989

    Open →
  • EPA DSSTox Identifiers

    chemistry · updated 2025-12-29

    Open →
  • FDA National Drug Code Directory

    regulatory · updated 2029-08-27

    Open →
  • FDA GSRS UNII

    registry · updated 2026-02-26

    Open →
  • openFDA Substance

    registry · updated 2026-05-24

    Open →
  • PubChem Live Enrichment

    chemistry · updated 2026-05-17

    Open →

Suitability

Context-specific fit derived from published classifications and the current ingredient evidence profile.

Fragrance avoidance

No fragrance-linked caution surfaced in the current profile.

Good fit

This ingredient does not currently read as a fragrance-linked driver in the published evidence and hazard profile.

Where it has been recorded

How often EPA CPDat has listed Hydrofluoric acid in a product composition. These are source records, not Greenveil catalog products.

Source records

450

Named organisations

6

Cleaning and safetyPersonal careSpecialty occupational productsLaboratory suppliesIndustrial productsCleaning products and household care

Typical roles

pH adjuster
See products using Hydrofluoric acid →